[可靠性建模及试验技术]重型机床液压元件油液污染退化量分布剖面可靠性建模

针对重型机床液压系统故障频繁且多与油液中的固态颗粒污染物相关的问题，进行了油液污染趋势变化试验。通过时域分析获得了油样颗粒数的有量纲和量纲一参数，通过Q-Q图和K-S检验分析有量纲参数，污染颗粒数是退化量服从正态分布的退化数据。进行了油液污染与环境相关性分析试验，采用相关系数法分析得到，颗粒数变化量与一定范围内的温度、流量、压力的相关性小；将液压元件分为管路、阀、过滤器三类，用直径5 μm左右的颗粒和直径大于15 μm的颗粒分别研究管路及阀件的堵塞和磨损情况，以过滤器过滤精度大小的颗粒研究过滤器的堵塞情况，设定ISO4406标准20/17级对应的颗粒数为阈值，利用退化量分布建立了液压元件单一故障模式的可靠性模型；利用竞争失效模型将上述模型融合为多故障模式下的可靠性模型。     

Photoactive Earth‐Abundant Iron Pyrite Catalysts for Electrocatalytic Nitrogen Reduction Reaction

The generation of ammonia, hydrogen production, and nitrogen purification are considered as energy intensive processes accompanied with large amounts of CO₂ emission. An electrochemical method assisted by photoenergy is widely utilized for the chemical energy conversion. In this work, earth‐abundant iron pyrite (FeS₂) nanocrystals grown on carbon fiber paper (FeS₂/CFP) are found to be an electrochemical and photoactive catalyst for nitrogen reduction reaction under ambient temperature and pressure. The electrochemical results reveal that FeS₂/CFP achieves a high Faradaic efficiency (FE) of ≈14.14% and NH₃ yield rate of ≈0.096 µg min^?1 at ?0.6 V versus RHE electrode in 0.25 m LiClO₄. During the electrochemical catalytic reaction, the crystal structure of FeS₂/CFP remains in the cubic pyrite phase, as analyzed by in situ X‐ray diffraction measurements. With near‐infrared laser irradiation (808 nm), the NH₃ yield rate of the FeS₂/CFP catalyst can be slightly improved to 0.1 µg min^?1 with high FE of 14.57%. Furthermore, density functional theory calculations demonstrate that the N₂ molecule has strong chemical adsorption energy on the iron atom of FeS₂. Overall, iron pyrite‐based materials have proven to be a potential electrocatalyst with photoactive behavior for ammonia production in practical applications.     

Can lanthanum doping enhance catalytic performance of silver in direct propylene epoxidation over NaMoAg/SiO_2?

In the attempt to reduce surface free energy of silica to improve interaction of silica with silver, silica was doped by different amounts of low surface energy lanthanum, La_2O_3, through impregnation. The doped and undoped silica were used as supports for preparation of Na/Ag/Mo/La_2O_3-SiO_2 catalysts. Catalytic performances of the catalysts were evaluated in direct epoxidation of propylene(DPO) using molecular oxygen under atmospheric pressure and without adding hydrogen. Adding 5 wt%La to the Na/Ag/Mo/SiO_2 catalyst improves both the catalysts electivity in DPO and its stability over 20h of time-on-stream.The characterization results show that La_2O_3 species interact strongly with silver particles on the silica surface which result in significant improvement in the dispersion profile of silver and marked decrease in the size of silver nanoparticles(AgNPs). The estimated mean diameter of AgNPs is ca. 4.0 nm in Na/Ag/Mo/5 wt%La_2O_3-SiO_2, which is smaller than that(53.9 nm) found in Na/Ag/SiO_2. The presence of subnanometer AgNPs on Ag/La_2O_3-SiO_2 prior addition of MoO_3 and NaCl to the sample can enhance the mutual electronic synergism between Ag, MoO_3 and Na for selective production of propylene oxide.     

Title加TextRank抽取关键句的情感分类研究

考虑到不同句子对判断文档情感倾向的重要程度不同，因而区分文档的关键句和细节句将有助于提高情感分类的性能。同时，考虑到Title和上下文信息，提出了一种基于Title和加权TextRank抽取关键句的情感分析方法SKTT，实现了高效的情感分析。根据文档Title的情感权重计算Title贡献度，考虑到标点和语义规则对情感倾向的影响；根据加权TextRank算法思想，在文档正文中构建了一个情感句有向图来提取关键句；计算所有关键句的情感倾向进行情感分类。在4个领域上进行实验，实验结果表明，该SKTT方法性能明显优于Baseline，具有高效性。     

Relations between asphaltene content,viscosity reduction rate of heavy oil and ultrasonic parameters

Ultrasonic treatment could decrease the viscosity of heavy oil and previous study on had focused on one heavy oil sample and involved less on the influence of asphaltene content. This study examined the effect of asphaltene content on viscosity reduction rate by ultrasonication. A comparison on samples with various asphaltene content and vibration parameter was made. The results showed that the optimal vibration frequency might decrease as the asphaltene content increased, whereas the optimal vibration intensity and the optimal treatment time were suggested to be enlarged. A semi-quantitative correlation was matched, which helped for numerical simulation about ultrasonic treatment.     

Systematic literature review on city logistics: overview,classification and analysis

City logistics is one of the significant branches of supply chain management, dealing with the logistics and transportation activities in urban areas. This research area has recently appropriated an exponential growth of publications. This paper presents a bibliometric analysis along with a systematic literature review to organise the results of surveying more than 370 papers and research works published since 2010. We identify the top contributing research topics. The most common keywords used in the city logistics literature are referred to in order to propose six research categories identifying the main innovative research perspectives.     

塔里木盆地中秋1凝析气藏成藏条件及演化过程

2018年12月,塔里木盆地秋里塔格构造带天然气勘探取得重大突破,中秋1井在下白垩统巴什基奇克组测试获高产工业气流,发现了该构造带迄今为止最大的整装凝析气藏。为了给该构造带下一步油气勘探部署提供依据,在充分利用前人研究成果的基础上,基于岩心、薄片、测井及地球化学分析资料,明确了中秋1大型凝析气藏的油气藏特征和气藏类型,分析了该气藏天然气成藏条件并推演其演化过程。研究结果表明:①中秋1大型气藏属于低含凝析油凝析气藏,天然气为煤成气,主要来自区内侏罗系腐殖型煤系烃源岩;②该构造带能够形成大型油气藏的有利地质条件是三叠系和侏罗系发育的两套巨厚高演化烃源岩、白垩系发育的大型辫状河三角洲规模有效砂岩储层、喜马拉雅晚期以来的构造活动形成的大规模楔状叠瓦构造圈闭、古近系和新近系巨厚膏盐岩形成的优越保存条件,以及油气生成与圈闭形成的良好时空匹配;③该气藏具有先油后气、晚期快速气侵聚集成藏的成藏模式,总体上是一个"早期聚油、晚期气侵、改造调整、快速成藏"的成藏过程。结论认为,该构造带油气成藏条件优越,具有广阔的油气勘探前景。     

柴达木盆地三湖坳陷横波勘探中的低幅异常消除技术

近年来,在柴达木盆地三湖坳陷开展了横波地震勘探,但是由于该区低幅度构造发育,横波静校正引起的"低幅"异常与上述低幅度构造相互混杂,难以区分。为此,针对该区横波表层调查难以控制表层横波速度模型的变化、横波近偏移距初至污染严重、横波折射层发育导致高速界面难以确定等问题,首先采用曲线拟合技术预测污染区横波初至时间确保初至完整性,然后采用面波模型与多层折射分层联合约束反演横波表层速度,最后通过基于速度谱分析的层位匹配建模技术确定合理的横波速度界面,形成了横波表层"低幅"异常消除技术,并进行了现场应用及效果评价。研究结果表明:①曲线拟合技术可以弥补近道污染区横波初至空白,保证层析反演模型的完整性;②基于瑞雷波的频散特性反演建模可以为确定该区浅层横波速度提供可靠的资料,提高浅层模型精度;③面波模型与多层折射分层联合约束反演能够更准确的反演该区表层横波速度场,较好地建立横波速度模型,消除横波剖面上"低幅"异常现象。结论认为,所形成的横波地震勘探低幅异常消除技术消除了横波静校正引起的"低幅"异常现象,提高了横波地震资料的成像品质。     

The isothermal reduction kinetics of chromium-bearing vanadium–titanium magnetite sinter

The reduction of chromium-bearing vanadium–titanium magnetite sinter (CVTMS) by CO was investigated at 1123–1223?K. The reduction degree increased with increasing temperature. The isothermal reduction kinetics of CVTMS was analysed, according to Sharp analysis and ln–ln analysis, the kinetic mechanism of reduction process for all samples in different basicity can be represented as f(α)?=?1.61(1?α)[?ln(1?α)]^1–1/1.61. The reaction activation energy of all samples (R?=?1.9, 2.1, 2.3, obtained according to the components of the materials burdening used in sintering process) at different reaction degrees were calculated by the model-free method. And the pre-exponential factors of reaction also were calculated by the mathematical method. The rate controlling step for the reduction process under the present reduction condition was chemical reaction.